Professor John Harding

MA PhD FRCS FinstP
Professor of Materials Simulation
Address:
Department of Materials Science and Engineering
Sir Robert Hadfield Building
Mappin Street, Sheffield, S1 3JD
Telephone: +44 (0) 114 222 5957
Fax: +44 (0) 114 222 5943
Email: j.harding@sheffield.ac.uk
John Harding joined the Department in 2004 from the Department of Physics and Astronomy, University College London.
Research interests
Real crystals stop somewhere and the boundaries, whether surfaces, grain boundaries or more complex interfaces often determine the behaviour. This is particularly true for nanomaterials, where a significant fraction of the atoms are at a boundary. The way crystals grow, their shape and structure is determined by the local environment.
The most spectacular example of this is the ability of living systems to grow minerals in complex shapes and sometimes unusual phases. Often, biominerals are nanocomposites – the combination of organic scaffold and mineral produces a material with unusual properties – for example the hardness of tooth enamel. We work closely with experimental groups, using simulations to understand how biomaterials are formed. This work is currently funded through an EPSRC programme grant "Hard-soft materials: from understanding to engineering" and involves collaborations both within Sheffield, nationally and internationally. Further details can be found on the link below.
We are also simulating the properties of interfaces as part of an EU programme to develop a multi-scale modelling framework for solar cells (Hipersol). This requires understanding the properties of the interfaces between the silver contact and silicon and also between the passivation layer and silicon and integrating this into a model of the solar cell. Further details can be found on the Hipersol link below.
The bulk properties of crystals, particularly transport properties, are often determined by point defects, either intrinsic, deliberately added or just happen to be there. Understanding the behaviour of defects, interfaces and how they control crystal properties needs simulation at the atomic scale (and often at longer scales as well). We use simulations to understand the properties of a variety of electroceramics, working with other members of the Ceramics and Composites Laboratory. A combination of atomistic and finite element methods is used to understand experimental impedance data.
Simulations are also being used to help develop new materials for encapsulating high-level nuclear waste by looking at the effects of radiation damage on several candidate materials in collaboration with Daresbury Laboratory and the University of Bristol.
The group therefore use a variety of methods: static lattice calculations, molecular dynamics, kinetic Monte Carlo, quantum (ab initio) methods, mesoscale (coarse-grained) and finite element simulations in conjunction with experiment to try and understand materials at all appropriate length and timescales.
Key projects
- Simulation of biomaterials, biomineralisation and biomolecules at ceramic surfaces. See www2.warwick.ac.uk/fac/sci/csc/collab/mib/overview
- Macromolecular structures and their chemical and physical influences on cell-surface binding interactions. See www.shef.ac.uk/cell-mineral
- Hipersol (Modelling of interfaces for high performance solar cell materials). See www.sintef.org/Projectweb/HiperSol
- Modelling electroceramic materials, especially ferroelectrics and lithium battery cathode materials. See www.shef.ac.uk/ccl
- Simulations of radiation damage and the development of waste-forms to encapsulate high-level nuclear waste. See www.immobilisation.net
Professional activities and recognition
- EPSRC Peer Review College
- Organiser of the annual CCP5 Summer School in Molecular Simulation
- Symposium Organiser, Fall MRS Meeting, 2008-2011
Key publications
- C. L. Freeman, F. Claeyssens, N.L. Allan and J.H. Harding, ‘Graphitic nanofilms as precursors to wurtzite films: theory’, Phys. Rev. Lett. 96 (2006) 066102.
- R. Carter, J. Sloan, A.I. Kirkland, R.R.Meyer, P.J.D. Lindan, G. Lin, M.L.H. Green, A. Vlandas, J.L. Hutchison and J. Harding, Correlation of structural and electronic properties in a new low-dimensional form of mercury telluride, Phys Rev Lett 96 (2006): Art. No. 215501.
- J. H. Harding, D.M. Duffy, M. Sushko, P.M. Rodger, D. Quigley and J.A. Elliott, Computational Techniques at the organic-inorganic interface in biomineralisation. Chem. Rev. 108 (2008) 4823-4854.
- C.L. Freeman, J.H. Harding, D. Quigley and P.M. Rodger, Structural control of crystal nuclei by an eggshell protein. Angew. Chim. Intl. 49 (2010) 5135-5137
- D. Quigley, C.L. Freeman, J.H. Harding and P.M. Rodger, Sampling the structure of calcium carbonate nanoparticles with metadynamics. J. Chem. Phys. 134 (2011) 044703.
Research group
Research Assistants (postdocs)
Dr Colin Freeman
Dr Keith Butler
Dr Julian Dean
Dr Henry Foxhall (jointly with Dr Karl Travis)
Dr Bo Christiansen (in collaboration with Prof. Susan Stipp, University of Copenhagen)
Research students
Mr Hungru Chen
Mr James Dawson
Mr David Sparkes
Research themes/centres
Nanomaterials and nanoengineering
Computer modelling and simulation
Immobilisation Science Laboratory
Ceramics and Composites Laboratory
Teaching
- MAT1110 Introduction to Materials Chemistry
- MAT1410 Biomaterials I
- MAT1920 Cradle to ? Materials and the Environment
- MAT4600 Multiscale materials modelling
- MAT6513 Physical Properties of Materials
- MAT6516 Materials for energy
Links
EPSRC atomistic simulation network CCP5
Programme Grant: “Hard-soft interfaces: from understanding to engineering"
Materials Chemistry Consortium
MESAS (Multiscale Engineering and science Simulations at Sheffield)
