Prof Anthony J Ryan OBE

Prof Anthony J Ryan

Phone: +44 (0)114 222 9760
Personal Assistant: +44 (0)114 222 9761
(Angela Simonite)
Room Number: D42

email : pvcscience@sheffield.ac.uk

Pro-Vice Chancellor, Faculty of Science:
BSc, Manchester (1983); PhD, Manchester (1988); DSc UMIST (2004)

Key Words

Polymer Nanotechnology (synthesis, processing, self-assembly, structure-property relations),
Public engagement in science and technology.

Research Interests

The common theme in my research is phase transitions in polymers. Most recently we have used the knowledge of the thermodynamics and kinetics of phase behaviour in polymer blends and block copolymers to develop new processing methods based on self-assembly. This has led to the development of the new field of Soft Nanotechnology where synthetic and natural macromolecules are harnessed in a way that makes use of their intrinsic flexibility and susceptibility to Brownian motion to generate work from changes on molecular conformation. Developments in polymers responsive to their environment have lead to research into molecular machines, specifically the fabrication of molecular valves and motors.

We do polymer synthesis in order to have well defined systems to study. The dynamics of phase behaviour are studied by calorimetry, spectroscopy, rheology, microscopy and light, X-ray or neutron scattering. A full suite of microstructural analysis (atomic force, optical and electron microscopy, X-ray diffraction and mechanical testing) is used to confirm the dynamic experiments and where appropriate computer modelling is also used.

My main contribution to the field has been the development and application of the techniques of time-resolved structural tools to polymers. This work was the subject of prizes in 1990 by the Plastics and Rubber Institute, in 1992, 1999 and 2003 from the Royal Society of Chemistry and in 1999 from the Polymer Processing Society.

I have been active in promulgating the public understanding of science since my graduate student days. This culminated in my appointment as the Royal Institution Christmas Lecturer for 2002 where my theme was the science and technology of everyday things. The lectures were seen on Channel 4 by 4.5 million viewers and have also been broadcast in Europe, Japan and Korea. I was also the 1st EPSRC Senior Media Fellow to allow me to combine world-class research and popular understanding of the impact of science and technology on society. I was awarded an OBE in 2005 for "services to science".

Selected Publications

  • Ryan, Anthony J.; Jones, Richard A. L. Polymers: the quest for motility. Materials Today (Oxford, United Kingdom) (2008), 11(7-8), 20-23.
  • Ferrer, M. Carme Coll; Babb, David; Ryan, Anthony J.. Characterisation of polyurethane networks based on vegetable derived polyol. Polymer (2008), 49(15), 3279-3287.
  • Mykhaylyk, Oleksandr O.; Chambon, Pierre; Graham, Richard S.; Fairclough, J. Patrick A.; Olmsted, Peter D.; Ryan, Anthony J.. The Specific Work of Flow as a Criterion for Orientation in Polymer Crystallization. Macromolecules (2008), 41(6), 1901-1904.
  • Lomas, Hannah; Canton, Irene; MacNeil, Sheila; Du, Jianzhong; Armes, Steven P.; Ryan, Anthony J.; Lewis, Andrew L.; Battaglia, Giuseppe. Biomimetic pH sensitive polymersomes for efficient DNA encapsulation and delivery. Advanced Materials (2007), 19(23), 4238-4243.
  • Wang, Linge; Topham, Paul D.; Mykhaylyk, Oleksandr O.; Howse, Jonathan R.; Bras, Wim; Jones, Richard A. L.; Ryan, Anthony J.. Electrospinning pH-responsive block copolymer nanofibers. Advanced Materials (2007), 19(21), 3544-3548. C
  • “Bilayers and Interdigitation in Block Copolymer Vesicles.” G. Battaglia and A.J. Ryan, Journal of the American Chemical Society, 127, 8757-8764 (2005).
  • “Responsive brushes and gels as components of soft nanotechnology” A.J. Ryan, C.J. Crook, J.R. Howse, P. Topham, R.A.L. Jones, M. Geoghegan, A.J. Parnell, L. Ruiz-Perez, S.J. Martin, A. Cadby, A. Menelle, J.R.P. Webster, A.J. Gleeson, W. Bras, Faraday Discussions, 128, 55-74.(2004).
  • “Early stages of crystallization in isotactic polypropylene.” E.L. Heeley, A.V. Maidens, P.D. Olmsted, W. Bras, I.P. Dolbnya, J.P.A. Fairclough, N.J. Terrill, A.J. Ryan, Macromolecules 36, 3656-3665 (2003).
  • “Ordered melts of block copolymers of ethylene oxide and 1,2-butylene oxide.” A.J. Ryan, S-M. Mai, J.P.A. Fairclough, I.W. Hamley, C. Booth, Phys. Chem. Chem. Phys., 3, 2961-2971 (2001).
  • “Lamellar phases and microemulsions in model ternary blends containing amphiphilic block copolymers.” L. Corvazier, L. Messe, C.L.O. R.N. Young, J.P.A. Fairclough, A.J. Ryan, Anthony J.. Journal of Materials Chemistry 11, 2864-2874 (2001).